Natural Resources Research Articles

The influence of particle size and mineralogy on both phosphorus retention and release by streambed sediments

Document Type

Article

Publication Date

2-9-2019

Journal Title

Journal of Soils and Sediments

ISSN

Print: 1439-0108 Electronic: 1614-7480

Keywords

Lateritic, Particle size, Phosphorus, Sediment, Surface area

Disciplines

Fresh Water Studies | Natural Resources Management and Policy | Soil Science | Water Resource Management

Abstract

Purpose

In many streams worldwide including those on the south coast of Western Australia (WA), sediments of the > 2-mm fraction often contribute up to 50% of the streambed. However, most analysis and interpretation of sediment chemistry, including phosphorus (P), is conducted on the < 2-mm fraction as this fraction is considered the most chemically reactive. This paper aims to identify the contribution of the > 2-mm fraction to P retention and release in sandy-gravely streams.

Material and methods

Sediment samples were collected from streams in agricultural catchments, and P retention and release by the < 2-mm and > 2-mm (typically lateritic; iron rich) sediment fractions were examined using fluvarium and batch experiments. Phosphorus sorbed by sediment was estimated on a mass (mg P kg−1) and area basis (mg P m−2).

Results and discussion

Phosphorus sorption measurements suggested that mineralogy as well as particle size were important factors influencing P retention by stream sediments. Stream sediments retained approximately 30% of added P. In a desorption phase, approximately 8% of the retained P was released into stream water.

Conclusions

Stream sediments in south western WA appear to be net immobilisers of P, retaining more P than they release, dependent on the stream P concentration. Exclusion of the > 2-mm fraction when determining stream sediment P dynamics may therefore underestimate whole stream sediment P retention and release.

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Digital Object Identifier (DOI)

https://doi.org/10.1007/s11368-019-02267-w