Natural Resources Research Articles

The role of soil organic matter in the geochemical cycling of chloride and bromide

Document Type

Article

Publication Date

3-27-2003

Journal Title

Journal of Hydrology

ISSN

ISSN: 0022-1694, eISSN: 1879-2707

Disciplines

Hydrology | Soil Science

Abstract

Chloride to bromide ratios were determined for rainfall in Western Australia and groundwaters and surface waters from a number of catchments in Western Australia, Victoria and Queensland. The ratio in rainfall, though showing a large short-term scatter, on average reflected the ratio in ocean water. Groundwaters and surface waters often showed characteristic differences in Cl−Br−, presumably associated with the cycling of bromide through soil organic matter. To prove this association it is shown that in the leachate of saturated small columns of soil the Cl−Br− ratio is governed by chloride and bromide, released from decomposing organic matter. On leaching the columns of soil the Cl−Br− weight ratio decreased rapidly from a high 300, reflecting rainfall, to a low 10, reflecting the ratio of chlorine to bromine bound to soil organic matter.

Share

COinS
 

Digital Object Identifier (DOI)

https://doi.org/10.1016/0022-1694(88)90029-7